2014 -the xiao group

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2014

124．Asymmetric trapping of zwitterionic intermediates by sulphur ylides in a palladium-catalysed decarboxylation-cycloaddition sequence Li, T.-R. Tan, F. Lu, L.-Q.* Wei, Y. Wang, Y.-N. Liu, Y.-Y.. Yang Q.-Q. Chen, J.-R. Shi D.-Q. Xiao, W.-J.* Nat. Commun.2014, 5,5500 DOI: 10.1038/ncomms6500

123. Photocatalytic Generation of N-Centered Hydrazonyl Radicals: A Strategy for Hydroamination of b,g-Unsaturated Hydrazones Hu, X.-Q. Chen, J.-R.* Wei, Q. Liu, F.-L. Deng, Q.-H. André. M. Beauchemin. Xiao, W.-J.* Angew. Chem. Int. Ed.2014,53,12163-12167. (Synfacts2014, 10, 1258) DOI: 10.1002/anie.201406491

122．Visible Light Photoredox Catalysis in Trifluoromethylation Reactions Zeng, T.-T. Xuan, J. Chen, J.-R. Lu, L.-Q.* Xiao, W.-J.* Imaging Science and Photochemistry2014,32, 415-432 DOI: 10.7517/j.issn.1674-0475.2014.05.415（Invited）

121. Synthesis of 2-Substituted Indoles through Visible Light-Induced Photocatalytic Cyclizations of Styryl Azides Xia, X.-D. Xuan, J. Wang, Q. Lu, L.-Q. Chen, J.-R.* Xiao, W.-J.* Adv. Synth. Catal.2014, 356, 2807-2812. DOI: 10.1002/adsc.201400527

120．Asymmetric Diels-Alder Reaction of 2-Arylidene-1,3-indanediones with 2-Vinylindoles Catalyzed by a Sc(OTf)3/Bis(oxazoline) Complex：Enantioselective Synthesis of Tetrahydrocarbazole Spiro Indanedio Tan F. Chen, J.-R. Wang, P.* Xiao, W.-J.* Acta Chim. Sinica.2014,72, 836-840 DOI: 10.6023/A14040237

119．Palladium/sulfoxide–phosphine-catalyzed highly enantioselective allylic etherification and amination Feng, B. Cheng, H.-G., Chen, J.-R. * Deng, Q.-H. Lu, L.-Q. Xiao, W.-J.* Chem. Commun.2014, 50, 9550-9553 DOI: 10.1039/C4CC03920C

118．Three-Component Coupling Reaction Triggered by Insertion of Arynes into the S═O Bond of DMSO Liu, F.-L. Chen, J.-R. * Zou, Y.-Q. Wei, Q. Xiao, W.-J.* Org. Lett.2014,16, 3768-3771 DOI: 10.1021/ol501638x

117．Photocatalytic aerobic oxidation/semipinacol rearrangement sequence: a concise route to the core of pseudoindoxyl alkaloids Ding, W. Zhou, Q.-Q. Xuan, J. Li, T.-R. Lu L.- Q.* Xiao, W.-J.* Tetrahedron Lett.2014, 55,4648-4652 DOI: 10.1016/j.tetlet.2014.06.102

116．De Novo Synthesis of Imidazoles by Visible-Light-Induced Photocatalytic Aerobic Oxidation/[3+2] Cycloaddition/Aromatization Cascade Deng, Q.-H. Zou, Y.-Q. Lu, L.-Q. Tang, Z.-L.Chen, J.-R. Xiao, W.-J. Chem. Asian. J.2014, 9, 2432-2435 DOI: 10.1002/asia.201402443

115．Enantioselective Synthesis of Tetrahydrofuran Derivatives by Sequential Henry Reaction and Iodocyclization of γ,δ-Unsaturated Alcohols Chen,L.-Y. Chen,J.-R.* Cheng,H.-G. Lu, L.-Q Xiao, W.-J.* Eur. J. Org. Chem.2014, 2014, 4714-4719 DOI: 10.1002/ejoc.201402396

114. Visible-light-induced photocatalytic formyloxylation reactions of 3-bromooxindoles with water and DMF: the scope and mechanism Zou, Y.-Q.Guo, W.Liu, F.-L.Lu, L.-Q. Chen, J.-R.* Xiao, W.-J.* Green Chem.2014, 16,3787-3795 DOI:10.1039/C4GC00647J

113．De Novo Synthesis of γ,γ-Disubstituted Butyrolactones through a Visible Light Photocatalytic Arylation–Lactonization Sequence Guo, W. Cheng, H.-G. Chen,L.-Y. Xuan, J. Feng,Z.-J. Chen, J.-R. Liang-Qiu Lu, L.-Q.* and Xiao, W.-J.* Adv. Synth. Catal.2014, 356,2787-2793. DOI: 10.1002/adsc.201400041

112．Enantio- and Diastereoselective Synthesis of Spiro-Epoxyoxindoles Boucherif, A. Yang, Q.-Q. Wang, Q. Chen, J.-R. Lu, L.-Q.* Xiao, W.-J. * J. Org. Chem.2014,79, 3924-3929 DOI: 10.1021/jo500385

111．Visible-Light-Induced Formal [3+2] Cycloaddition for Pyrrole Synthesis under Metal-Free Conditions Xuan, J. Xia, X.-D. Zeng, T.-T. Feng, Z.-J. Chen, J.-R. Lu, L.-Q.* Xiao, W.-J.* Angew. Chem. Int. Ed.2014,53, 5653-5656. DOI: 10.1002/ anie.201400602

110. Efficient Synthesis of Dihydropyrazoles by Halocyclization of β,γ-Unsaturated Hydrazones Hu, X.-Q. Chen, J.-R.* Wei, Q. Liu, F.-L. Deng, Q.-H. Zou, Y.-Q. Xiao, W.-J.* Eur. J. Org. Chem.2014, 2014, 3082-3086 DOI: 10.1002/ejoc.201402021

109. Metal-Containing Carbonyl Ylides: Versatile Reactants in Catalytic Enantioselective Cascade Reactions† Chen, J.-R.Hu, X.-Q. Xiao, W.-J. Angew. Chem. Int. Ed.2014,53, 4038-4040 DOI: 10.1002/anie.201400018

108. Aerobic oxidative C– B bond cleavage of arylboronic acids mediated by methylhydrazines Ding, W. Chen, J.-R.* Zou, Y.-Q. Duan, S.-W. Lu L.- Q. Xiao, W.-J.* Org. Chem. Front.2014, 1,151-154. DOI: 10.1039/C3QO00026E

107. Visible Light-Induced C-S Bond Activation: Facile Access to 1,4-Diketones from β-Ketosulfones Xuan, J. Feng, Z.-J. Chen, J.-R. Lu, L.-Q.* Xiao, W.-J.* Chem. Eur. J.2014,20, 3045-049 DOI: 10.1002/chem.201304898

106. Organocatalytic Asymmetric Conjugate Addition of 2-Oxindole-3-Carboxylate Esters to 2-Phthalimido Acrylates: Efficient Synthesis of Cγ-tetrasubstituted α-Amino Acid Derivatives Gao, J. Chen, J.-R.* Duan, S.-W. Li, T.-R. Lu, L.-Q. Xiao, W.-J. * Asi.J. Org. Chem.2014,3, 530-535. DOI: 10.1002/ajoc.201300292

105．Enantioselective Cascade Michael Addition/Cyclization Reactions of 3-Nitro-2H-Chromenes with 3-Isothiocyanato Oxindoles: Efficient Synthesis of Functionalized Polycyclic Spirooxindoles Tan, F. Lu, L.-Q. Yang, Q.-Q. Guo, W. Bian, Q. Chen, J.-R.* Xiao, W.-J.* Chem. Eur. J.2014, 20,3415-3420 DOI: 10.1002/chem.201303583

104. Direct sp3 C-H acroleination of N-aryl-tetrahydroisoquinolines by merging photoredox catalysis with nucleophilic catalysis Feng, Z.-J. Xuan, J. Xia, X.-D. Ding, W. Guo, W. Chen, J.-R. Zou, Y.-Q. Lu, L.-Q.* and Xiao, W.-J. * Org. Biomol. Chem.2014,12, 2037 - 2040 DOI: 10.1039/c3ob42453g

103．Synthesis of CF3-Containing 3,3′-Cyclopropyl Spirooxindoles by Sequential [3 + 2] Cycloaddition/Ring Contraction of Ylideneoxindoles with 2,2,2-Trifluorodiazoethane Li, T.-R. Duan, S.-W. Ding, W. Liu, Y.-Y. Chen, J.-R. Lu, L.-Q.* Xiao, W.-J.* J. Org. Chem.2014,79, 2296-2302 DOI: 10. 1021/jo50019a

102. Rational design of sulfoxide-phosphine ligands for Pd-catalyzed enantioselective allylic alkylation reactions Cheng, H.-G. Feng, B. Chen, L.-Y. Guo, W. Yu, X.-Y. Lu, L.-Q. Chen, J.-R. * Xiao, W.-J.* Chem. Commun.2014,50,2873-2875. DOI: 10.1039/C3CC49488H

101. Enantioselective organocatalytic oxa-Michael addition of oximes to β-CF3-β-disubstituted nitroalkenes: efficient synthesis of β-amino-α-trifluoromethyl alcohols Liu, F.-L. Chen, J.-R.* Feng, B. Hu, X.-Q. Ye, L.-H. Lu, L.-Q. Xiao, W.-J.* Org. Biomol. Chem.,2014,12, 1057-1060 DOI: 10.1039/C3OB42329H